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The Chemistry Behind Storage and Stability Rules Glutathione degrades primarily through two pathways: (1) oxidation of the cysteine thiol to form GSSG (reversible in vivo but irreversible once significantly advanced in solution), and (2) hydrolysis of the gamma-glutamyl peptide bond, which is the same bond cleaved by gamma-glutamyltransferase in the intestine and on cell surfaces

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As extracellular glutamine levels decline, asparagine becomes an essential amino acid