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Its structure is Ac-Nle-cyclo[Asp-His-D-Phe-Arg-Trp-Lys]-NH₂: the ring is closed by a lactam bridge between the Asp side-chain and the Lys side-chain, and the norleucine (Nle) and D-phenylalanine substitutions rigidify the pharmacophore — the structural basis for its receptor affinity and metabolic stability relative to native α-MSH

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Several conditions can produce dark patches in the mouth, and most are completely benign